Metal is mentioned in the Quran in these verses:

[13:17] He sends down water from the sky, causing the valleys to overflow, then the rapids produce abundant foam. Similarly, when they use fire to refine metals for their jewelry or equipment, foam is produced. God thus cites analogies for the truth and falsehood. As for the foam, it goes to waste, while that which benefits the people stays close to the ground. God thus cites the analogies.

[55:35] You get bombarded with projectiles of fire and metal, and you cannot win.

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